2022

Five-Spin Supramolecule for Simulating Quantum Decoherence of Bell States

S. J. Lockyer, A. Chiesa, A. Brookfield, G. A. Timco, G. F. S. Whitehead, E. J. L. McInnes, S. Carretta, R. E. P. Winpenny, J. Am. Chem. Soc., 2022, doi: 10.1021/jacs.2c06384.

Decorating polymer beads with 10^14 inorganic-organic [2]rotaxanes as shown by spin counting

D. Asthana, D. Thomas, S. J. Lockyer, A. Brookfield, G. A. Timco, I. J. Vitorica-Yrezebal, G. F. S. Whitehead, E. J. L. McInnes, D. Collison, D. A. Leigh, R. E. P. Winpenny, Comm. Chem., 2022, doi: 10.1038/s42004-022-00689-1.

Dry heterometallic resist processing based on thermal sublimation deposition and development

D. L. Goldfarb, S. M. Lewis, R. Grindell, G. A. Timco, R. E. P. Winpenny, Journal of Micro/Nanopatterning, Materials, and Metrology, 2022, doi: 10.1117/1.JMM.21.4.041406.

Modelling Conformational Flexibility in a Spectrally Addressable Molecular Multi-Qubit Model System

Ciaran. J. Rogers, D. Asthana, A. Brookfield, A. Chiesa, G. A. Timco, D. Collison, L. S. Natrajan, S. Carretta, R. E. P. Winpenny, A. M. Bowen, Angew. Chem. Int. Ed., 2022, doi: 10.1002/anie.202207947.

Tuning the Performance of Negative Tone Electron Beam Resists for the Next Generation Lithography

S. M. Lewis, G. A. DeRose, H. R. Alty, M. S. Hunt, N. Lee, J. A. Mann, R. Grindell, A. Wertheim, L. De Rose, A. Fernandez, C. A. Muryn, G. F. S. Whitehead, G. A. Timco, A. Scherer, R. E. P. Winpenny, Adv. Funct. Mater., 2022, doi: 10.1002/adfm.202202710.

2021

A Cost-Effective Semi-Ab Initio Approach to Model Relaxation in Rare-Earth Single-Molecule Magnets

E. Garlatti, A. Chiesa, P. Bonfa, E. Macaluso, I. J. Onuirah, V. S. Parmar, Y. Ding, Y. Zheng, M. J. Giansiracusa, D. Reta, E. Pavarini, T. Guidi, D. P. Mills, N. F. Chilton, R. E. P. Winpenny, P. Santini, S. Carretta, J. Phys. Chem. Lett., 2021, doi: acs.jpclett.1c02367.

Mononuclear Dysprosium Alkoxide and Aryloxide Single—Molecule Magnets

V. S. Parmar, D. P. Mills, R. E. P. Winpenny, Chem. Eur. J., 2021, doi: 10.1002/chem.202100085.

Single Isomer Heterometallic {CrIII6MII2} Rings Templated by Tetramethylammonium

R. Alotaibi, E. Little, J. M. Fowler, A. Brookfield, R. W. Adams, A. Achari, G. A. Timco, G. F. S Whitehead, N. F. Chilton, R. R. Nair, D. Collison, R. E. P. Winpenny, Inorg. Chem., 2021, doi: 10.1021/acs.inorgchem.1c02342.

Magnetic Properties and Second Harmonic Generation of Noncentrosymmetric Cyanido-Bridged Ln(III)�W(V) Assemblies

K. Kumar, O. Stefanczyk, N. F. Chilton, K. Nakabayashi, K. Imoto, R. E. P. Winpenny, S. Ohkoshi, Inorg. Chem., 2021, doi: 10.1021/acs.inorgchem.1c01113.

Studies of the Temperature Dependence of the Structure and Magnetism of a Hexagonal-Bipyramidal Dysprosium(III) Single-Molecule Magnet

Y. Ding, W. J. A. Blackmore, Y. Zhai, M. J. Giansiracusa, D. Reta, I. Vitorica-Yrezabal, R. E. P. Winpenny, N. F. Chilton, Y. Zheng, Inorg. Chem., 2021, doi: 10.1021/acs.inorgchem.1c02779.

Targeting molecular quantum memory with embedded error correction

S. J. Lockyer, A. Chiesa, G. A. Timco, E. J. L. McInnes, T. S. Bennett, I. J. Vitorica-Yrezebal, S. Carretta, R. E. P. Winpenny, Chemical Science, 2021, doi: 10.1039/D1SC01506K.

Slow magnetic relaxation in distorted tetrahedral Dy(iii) aryloxide complexes

V. S. Parmar, G. K. Gransbury, G. F. S. Whitehead, D. P. Mills, R. E. P. Winpenny, Chem. Comm., 2021, doi: 10.1039/D1CC02707G.

Gold(I) bridged dimeric and trimeric heterometallic {Cr7Ni}-based qubit systems and their characterization

D. Asthana, S. J. Lockyer, S. Nawaz, R. J. Woolfson, G. A. Timco, C. A. Muryn, I. J. Vitorica-Yrezabal, D. Collison, N. A. Burton, R. E. P. Winpenny, Dalton Trans., 2021, doi: 10.1039/d1dt00150g.

The Synthesis and Characterisation of a Molecular Sea-Serpent: Studies of a {Cr24Cu7} Chain

R. Alotaibi, J. M. Fowler, S. J. Lockyer, G. A. Timco Prof. Dr. David Collison, J. Schnack, R. E. P. Winpenny, Angew. Chem. Int. Ed., 2021, doi: 10.1002/anie.202015731.

2020

Nanoscale Patterning of Zinc Oxide from Zinc Acetate Using Electron Beam Lithography for the Preparation of Hard Lithographic Masks

A. Chaker, H. R. Alty, P. Tian, A. Kotsovinos, G. A. Timco, C. A. Muryn, S. M. Lewis, R. E. P. Winpenny, ACS Appl. Nano. Mater., 2020, doi: 10.1021/acsanm.0c02756.

Heterometallic 3d-4f complexes as air-stable molecular pre-cursors in low temperature syntheses of stoichiometric rare-earth orthoferrite powders

M. M. Alsowayigh, G. A. Timco, I. Borilovic, A. Alanazi, I. J. Vitorica-yrezabal, G. F. S. Whitehead, P. D. McNaughter, F. Tuna, P. O’Brien, R. E. P. Winpenny, D. J. Lewis, D. Collison, Inorg. Chem., 2020, doi: 10.1021/acs.inorgchem.0c02249.

Magnetic Exchange Interactions in Symmetric Lanthanide Dimetallics

M. J. Giansiracusa, S. Al-Badran, A. K. Kostopoulos, G. F. S. Whitehead, E. J. L. McInnes, D. Collison, R. E. P. Winpenny, N. F. Chilton, Inorg. Chem. Front, 2020, doi: 10.1039/D0QI00854K.

Conformational flexibility of hybrid [3]- and [4]-rotaxanes

S. J. Lockyer, S. Nawaz, A. Brookfield, A. J. Fielding, I. J. Vitorica-Yrezabal, G. A. Timco, N. A. Burton, A. M. Bowen, R. E. P. Winpenny, E. J. L. McInnes, J. Am. Chem. Soc., 2020, doi: 10.1021/jacs.0c06547.

Dimerized p-Semiquinone Radical Anions Stabilized by a Pair of Rare-Earth Metal Ions

T. Han, J. B. Petersen, Z. Li, Y. Zhai, A. Kostopoulos, F. Ortu, E. J. L. McInnes, R. E. P. Winpenny, Y. Zheng, Inorg. Chem., 2020, doi: 10.1021/acs.inorgchem.0c00503.

Exchange-Biasing in a Dinuclear Dysprosium(III) Single-Molecule Magnet with a Large Energy Barrier for Magnetization Reversal

T. Han, M. J. Giansiracusa, Z. Li, Y. Ding, N. F. Chilton, R. E. P. Winpenny, Y. Zheng, Chem. Eur. J., 2020, doi: 10.1002/chem.202000719.

Probing relaxation dynamics in five-coordinate dysprosium single-molecule magnets

V. S. Parmar, F. Ortu, X. Ma, N. F. Chilton, R. Clérac, D. P. Mills, R. E. P. Winpenny, Chem. Eur. J., 2020, doi: 10.1002/chem.202001235.

A Study of Magnetic Relaxation in Dysprosium(III) Single-Molecule Magnets

Y. Ding, T. Han, Y. Zhai, D. Reta, N. F. Chilton, R. E. P. Winpenny, Y. Zheng, Chem. Eur. J., 2020, doi: 10.1002/chem.202000646.

2019

A Study of Magnetic Relaxation in Dysprosium(III) Single-Molecule Magnets

Y. Ding, T. Han, Y. Zhai, D. Reta, N. F. Chilton, R. E. P. Winpenny, Y. Zheng, Chem. Eur. J., 2020, doi: 10.1002/chem.202000646.

Close Encounters of the Weak Kind: Investigations of Electron-Electron Interactions between Dissimilar Spins in Hybrid Rotaxanes

S. J. Lockyer, A. J. Fielding, G. F. S. Whitehead, G. A. Timco, R. E. P. Winpenny and E. J. L. McInnes, J. Am. Chem. Soc., 2019, doi: 10.1021/jacs.9b05590.

A [13]rotaxane assembled via a palladium molecular capsule

J. Ferrando-Soria, A. Fernandez, D. Asthana, S. Nawaz, I. J. Victorica-Yrezabal, G. F. S. Whitehead, C. A. Muryn, F. Tuna, G. A. Timco, N. D. Burton and R. E. P. Winpenny, Nature Commun., 2019, doi: 10.1038/s41467-019-11635-6.

Studies of Hysteresis and Quantum Tunnelling of the Magnetisation in Dysprosium(III) Single Molecule Magnets

F. Ortu, D. Reta, Y. S. Ding, C. A. P. Goodwin, M. P. Gregson, E. J. L. McInnes, R. E. P. Winpenny, Y. Z. Zheng, S. T. Liddle, D. P. Mills and N. F. Chilton, Dalton Trans., 2019, doi: 10.1039/c9dt01655d.

Correlating Blocking Temperatures with Relaxation Mechanisms in Monometallic Single-Molecule Magnets with High Energy Barriers (Ueff > 600 K)

M. Giansiracusa, A. Kostopoulos, D. Collison, R. E. P. Winpenny and N. F. Chilton, Chem. Commun., 2019, doi:10.1039/c9cc02421b.

Formation of an interlocked double-chain from an organic-inorganic [2]rotaxane

J. Ferrando-Soria, A. Fernandez, I. J. Vitorica-Yrezabal, D. Asthana, C. A. Muryn, F. Tuna, G. A. Timco and R. E. P. Winpenny, Chem. Commun., 2019, 55, 2960-2963.

A Clock Transition in the Cr7Mn Molecular Nanomagnet

C. A. Collett, K. I. Ellers, N. Russo, K. R. Kittilstved, G. A. Timco, R. E. P. Winpenny and J. R. Friedman, Magnetochemistry, 2019, 5, 4.

Electric Field Control of Spins in Molecular Magnets

J. Liu, J. Mrozek, W. K. Myers, G. A. Timco, R. E. P. Winpenny, B. Kintzel, W. Plass and A. Ardavan, Phys. Rev. Lett., 2019, 122, 037202.

Transferability of the anisotropic spin model coupling parameters in a family of doped chromium-based molecular rings

M. Antkowiak, G. Kamineniarz, G. A. Timco, F. Tuna and R. E. P. Winpenny, J. Mag. Mag. Mat., 2019, 479, 166-169.

Thorium- and uranium-azide reductions: a transient dithorium nitride versus isolable diuranium nitrides

J. Du, D. M. King, L. Chatelain, E. Liu, F. Tuna, E. J. L. McInnes, A. J. Wooles, L. Maron and S. T. Liddle, Chem. Sci., 2019, 10, 3738-3745.

Rigidification of a macrocyclic tris-catecholate scaffold leads to electronic delocalisation of its mixed valent product

S. Greatorex, K. B. Vincent, A. Baldansurenm E. J. L. McInnes, N. J. Patmore, S. Sproules and M. A. Halcrow, Chem. Commun., 2019, 55, 2281-2284.

Light Lanthanide Metallocenium Cations Exhibiting Weak Equatorial Anion Interactions

J. Liu, D. Reta, J. Cleghorn, Y. X. Yeoh, F. Ortu, C. A. P. Goodwin, N. F. Chilton and D. P. Mills, Chem. Eur. J., 2019, 25, 1-11.

Sensitivity of Magnetic Anisotropy in the Solid State for Lanthanide Complexes with Small Crystal Field Splitting

M. Vonci, K. Mason, E. R. Neil, D. S. Yufit, E. J. L. McInnes, D. Parker and N. F. ChiltonInorg. Chem., 2019, 58, 5733-5745.

2018

Binding of halogens by a Cr8 metallocrown

D. F. Sava, N. Zheng, I. J. Vitorica-Yrezabal, G. A. Timco and R. E. P. Winpenny, Dalton Trans., 2018, 47, 13771-13775.

Field- and temperature-dependent quantum tunnelling of the magnetisation in a large barrier single-molecule magnet

Y. S. Ding, K. X. Yu, D. Reta, F. Ortu, R. E. P. Winpenny, Y. Z. Zheng and N. F. Chilton, Nature Commun., 2018, 9, 3134.

Hybrid organic-inorganic rotaxanes, including a hetero-hybrid [3]rotaxane featuring two distinct heterometallic rings and a molecular shuttle

G. A. Timco, A. Fernandez, A. K. Kostopoulos, J. F. Chilton, S. J. Lockyer, T. R. Hailes, R. W. Adams, E. J. L. McInnes, F. Tuna, I. J. Vitorica-Yrzebal, G. F. S. Whitehead and R. E. P. Winpenny, Angew. Chem. Int. Ed., 2018, 57, 10919-10922.

Quantum Monte Carlo Simulations of a Giant {Ni21Gd20} Cage with a S = 91 Spin Ground State

W. P. Chan, J. Singleton, L. Qin, A. Camon, L. Engelhardt, F. Luis, R. E. P. Winpenny and Y. Z. Zheng, Nature Commun., 2018, 9, 2107.

Chromium Chains as Polydentate Fluoride Ligands for Actinides and Group IV Metals

J. D. Leng, A. K. Kostopoulos, L. H. Isherwood, A. M. Ariciu, F. Tuna, I. J. Vitorica-Yrezabal, R. P. Pritchard, G. F. S. Whitehead, G. A. Timco, D. P. Mills and R. E. P. Winpenny, Dalton Trans., 2018, 47, 6361-6369.

Anisotropy of CoII transferred to the Cr7Co polymetallic cluster via strong exchange interactions

E. Garlatti, T. Guidi, A. Chiesa, S. Ansbro, M. L. Baker, J. Ollivier, H. Mutka, G. A. Timco, I. J. Vitorica-Yrezabal, E. Pavarini, P. Santini, G. Amoretti, R. E. P. Winpenny and S. Carretta, Chem. Sci., 2018, 9, 3555-3562.

Measurement of magnetic exchange in asymmetric lanthanide dimetallics: towards a transferable theoretical framework

M. J. Giansiracusa, E. Moreno-Pineda, R. Hussain, R. Marx, M. Dorfel, P. Neugebauer, S. Al-Badran, D. Collison, F. Tuna, J. van Slageren, S. Carretta, T. Guidi, E. J. L. McInnes, R. E. P. Winpenny and N. F. Chilton, J. Am. Chem. Soc., 2018, 140, 2504-2513.

Evidence of Spin Canting, Metamagnetism, Negative Coercivity and Slow Relaxation in a Two-Dimensional Network of {Mn6} Cages

C. Dendrinou-Samara, J. P. S. Walsh, C. A. Muryn, D. Collison, R. E. P. Winpenny and F. Tuna, Eur. J. Inorg. Chem., 2018, 2018, 485-492.

How to probe the spin contribution to momentum relaxation in topological insulators

M. S. Nam, B. H. Williams, Y. Chen, S. Contera, S. Yao, M. Lu, Y. F. Chen, G. A. Timco, C. A. Muryn and R. E. P. Winpenny, Nature Commun., 2018, 9, 56.

The synthesis of a monodispersed quaternary ferrite (FeCoCrO4) from the hot injection thermolysis of the single source precursor [CrCoFeO(O2CtBu)6(HO2CtBu)3

K. O. Abdulwahab, M. A. Malik, G. A. Timco, F. Tuna, R. E. P. Winpenny, I. Vitorica-Yrzebal and P. O’Brien, Dalton Trans., 2018, 47, 376-381.

Cages on a plane: a structural matrix for molecular 'sheets'

H. W. L. Fraser, G. S. Nichol, A. Baldansuren, E. J. L. McInnes and E. K. Brechin, Dalton Trans., 2018, 47, 15530-15537.

Modular [FeIII8MII6]n+ (MII = Pd, Co, Ni, Cu) coordination cages

S. Sanz, H. M. O’Connor, P. Comar, A. Baldansuren, M. B. Pitak, S. J. Coles, H. Weihe, N. F. Chilton, E. J. L. McInnes, P. J. Lusby, S. Piligkos and E. K. Brechin, Inorg. Chem., 2018, 57, 3500-3506.

Actinide-transition metal bonding in heterobimetallic uranium- and thorium-molybdenum paddlewheel complexes

A. J. Ayers, M. Zegke, J. P. A. Ostrowski, F. Tuna, E. J. L. McInnes, A. J. Wooles and S. T. Liddle, Chem. Commun., 2018, 54, 13515-13518.

Exquisite sensitivity of the ligand field to solvation and donor polarisability in coordinatively saturated lanthanide complexes

K. Mason, A. C. Harnden, C. Patrick, A. W. J. Poh, A. S. Batsanov, E. A. Suturina, M. Vonci, E. J. L. McInnes, N. F. Chilton and D. Parker, Chem. Commun., 2018, 54, 8486-8489.

Reversible adsorption of nitrogen dioxide within a robust porous metal-organic framework

X. Han, H. G. W. Godfrey, L. Briggs, A. J. Davies, Y. Cheng, L. L. Daemen, A. M. Sheveleva, F. Tuna, E. J. L. McInnes, J. Sun, C. Drathen, M. W. George, A. J. Ramirez-Cuesta, K. M. Thomas, S. Yang, and M. Schroder, Nature Mat., 2018, 17, 691-696.

Uranium(III)-carbon multiple bonding supported by arene d-bonding in mixed-valence hexauranium nanometre-scale rings

A. J. Wooles, D. P. Mills, F. Tuna, E. J. L. McInnes, G. Law, A. Fuller, F. Kremer, M. Ridgway, W. Lewis, L. Gagliardi, B. Vlaisavjevich, and S. T. Liddle, Nature Commun., 2018, 9, 2097.

Catalytic dinitrogen reduction to ammonia at a triamidioamine-titanium complex

L. R. Doyle, A. J. Wooles, L. C. Jenkins, F. Tuna, E. J. L. McInnes and S. T. Liddle, Angew. Chem. Int., 2018, 57, 6314-6318.

Exploring synthetic routes to heteroleptic UIII, UIV, and ThIV bulky bis(silyl)amide complexes

C. A. P. Goodwin, F. Tuna, E. J. L. McInnes and D. P. Mills, Eur. J. Inorg. Chem., 2018, 2018, 2356-2362.

Slow magnetic relaxation in a {EuCu5} metallacrown

J. Wang, Z. Y. Ruan, Q. W. Li, Y. C. Chen, G. Z. Huang, J. L. Liu, D. Reta, N. F. Chilton, Z. X. Wang and M. L. Tong, Dalton Trans., 2018, 48, 1686-1692.

Terbocenium: completing a heavy lanthanide metallocenium cation family with an alternative anion abstraction strategy

C. A. P. Goodwin, D. Reta, F. Ortu, J. Liu, N. F. Chilton and D. P. Mills, Chem. Commun., 2018, 54, 9182-9185.

Lanthanide-induced relaxation anisotropy

E. A. Suturina, K. Mason, C. F. G. C. Geraldes, N. F. Chilton, D. Parker and I. Kuprov, Phys. Chem. Chem. Phys., 2018, 20, 17676-17686.

Self-assembly of a mixed-valence FeII-FeIII tetranuclear star

D. Sertphon, P. Harding, K. S. Murray, B. Moubaraki, N. F. Chilton, S. Hill, J. Marbey, H. Adams, C. G. Davies, G. N. L. Jameson and D. J. Harding, Dalton Trans., 2018, 47, 7188-7122.

Iron Precatalysts with Bulky Tri(t-butyl)cyclopentadienyl Ligands for the Dehydrocoupling of Dimethylamine-Borane

J. Turner, N. F. Chilton, A. Kumar, A. L. Colebatch, G. R. Whittell, H. A. Sparkes, A. S. Weller and I. Manners, Chem. Eur. J., 2018, 24, 14127-14136.

2017

Low field spin dynamics of Cr7Ni and Cr7Ni-Cu-Cr7Ni molecular rings as detected by μSR

S. Sanno, P .Arosio, L. Bordonali, F. Adelnia, M. Mariani, E. Garlatti, C. Baines, A. Amato, K. P. V. Sabareesh, G. Timco, R. E. P. Winpenny, S. J. Blundell and A. Lascialfari, Phys. Rev. B., 2017, 96, 184403.

Quantum Monte Carlo Simulations and High-Field Magnetization Studies of Antiferromagnetic Interactions in a Giant Hetero-Spin Ring

L. Qin, J. Singleton, W. P. Chen, H. Nojiri, L. Engelhardt, R. E. P. Winpenny and Y. Z. Zheng, Angew. Chem. Chem. Int. Ed., 2017, 56, 16571-16574.

Topological Self-Assembly of Highly Symmetric Lanthanide Clusters: A Magnetic Study of Exchange-Coupling "Fingerprints" in Giant Gadolinium(III) Cages

L. Qin, G. J. Zhou, Y. Z. Yu, H. Nojiri, C. Schroder, R. E. P. Winnpeny and Y. Z. Zheng, J. Am. Chem. Soc., 2017, 139, 16405-16411.

The performance of density functional theory for the description of ground and excited state properties of inorganic and organometallic uranium compounds

D. Reta, F. Ortu, S. Randall, D. P. Mills, N. F. Chilton, R. E. P. Winpenny, L. Natrajan, B. Edwards and N. Kaltsoyannis, J. Organomet. Chem., 2017, 857, 58-74.

A sub-Kelvin cryogen-free EPR system

S. J. Melhuish, C. Stott, A. M. Ariciu, L. Martinis, M. McCulloch, L. Piccirillo, D. Collision, F. Tuna, R. E. P. Winpenny, J. Mag. Res. , 2017, 282, 83-88.

An extensive family of heterometallic titanium(IV)-metal(III) rings with structure control through templates

G. A. Timco, A. Fernandez, A. K. Kostopoulos, C. A. Muryn, R. G. Pritchard, I. Strashnov, I. J. Vitorica-Yrezebal, G. F. S. Whitehead and R. E. P. Winpenny, Chem. Int. Ed., 2017, 56, 13629-13632.

Quart Crystal Microbalance Assay of Clinical Calcinosis Samples and Their Synthetic Models Differentiates the Efficacy of Chelation-Based Treatments

F. Fei, A. Gallas, Y. C. Chang, Y. Rao, A. C. Hunter, R. E. P. Winpenny, A. L. Herrick, N. P. Lockyer and C. F. Blanford, ACS Appl. Mater. Interfaces., 2017, 9, 27544-27552.

Actinide covalency measured by pulsed electron paramagnetic resonance spectroscopy

A. Formanuik, A-M. Ariciu, F. Ortu, R. Beekmeyer, A. Kerridge, F. Tuna, E. J. L. McInnes and D. P. Mills, Nature Chemistry, 2017, 9, 578-583.

Rationalization of Anomalous Pseudocontact Shifts and Their Solvent Dependence in a Series of C3-Symmetric Lanthanide Complexes

M. Vonci, K. Mason, E. A. Suturina, A. T. Frawley, S. G. Worswick, I. Kuprov, D. Parker, E. J. L. McInnes and N. F. Chilton, J. Am. Chem. Soc., 2017, 139, 14166-14172.

Evidence for Single Metal Two Electron Oxidative Addition and Reductive Elimination at Uranium

B. M. Gardner, C. E. Kefalidis, E. Lu, D. Patel, E. J. L. McInnes, F. Tuna, A. J. Wooles, L. Maron and S. T. Liddle, Nature Commun., 2017, 8, 1898.

Molecular magnetic hysteresis at 60 kelvin in dysprosocenium

C. A. P. Goodwin, F. Ortu, D. Reta, N. F. Chilton and D. P. Mills, Nature, 2017, 548, 439-442.

Metallacrowns as Templates for Diabolo-like {LnCu8} Complexes with Nearly Perfect Square Antiprismatic Geometry

G. J. Zhou, T. Han, Y. S. Ding, N. F. Chilton and Y. Z. Zheng, Chem. Eur. J., 2017, 23, 15617-15622.

Magnetic Exchange Interactions in the Molecular Nanomagnet Mn{12}

A. Chiesa, T. Guidi, S. Carretta, S. Ansbro, G. A. Timco, I. Vitorica-Yrezabal, E. Garlatti, G. Amoretti, R. E. P. Winpenny and P. Santini, Phys. Rev. Lett., 2017, 119, 217202.

Antimony-Ligated Dysprosium Single-Molecule Magnets as Catalysts for Stibine Dehydrocoupling

T. Pugh, N. F. Chilton and R. A. Layfield, Chem. Sci., 2017, 8, 2073-2080.

Rare Earth- and Uranium-Mesoionic Carbenes: A New Class of f-Block Carbene Complex Derived from an N-Heterocyclic Olefin

J. A. Seed, M. Gregson, F. Tuna, N. F. Chilton, A. J. Wooles, E. J. L. McInnes and S. T. Liddle, Angew. Chem. Int. Ed., 2017, 56, 11534-11538.

Molecules Designed to Contain Two Weakly Coupled Spins with a Photo-switchable Spacer

J. Salinas-Uber, M. Estrader, J. Garcia, P. Lloyd-Williams, A. Sadurni, D. Dengler, J. van Slageren, N. F. Chilton, O. Roubeau, S. Teat, J. Ribas-Arino and G. Aromi, Chem. Eur. J., 2017, 23, 13648-13659.

Assessing Crystal Field and Magnetic Interactions in Diuranium-μ-Chalcogenide Triamidoamine Complexes With UIV-E-UIV Cores (E = S, Se, Te): Implications for Determining the Presence or Absence of Actinide-Actinide Magnetic Exchange

B. Gardner, D. M. King, F. Tuna, A. Wooles, N. F. Chilton and S. Liddle, Chem. Sci., 2017, 8, 6207-6217.

Use of Supramolecular Assemblies as Lithographic Resists

S. M. Lewis, A. Fernandez, G. A. DeRose, M. S. Hunt, G. F. S. Whitehead, A. Lagzda, H. R. Alty, J. Ferrando-Soria, S. Varey, A. K. Kostopoulos, F. Schedin, C. A. Muryn, G. A. Timco, A. Scherer, S. G. Yeates and R. E. P. Winpenny, Angew. Chem. Int. Ed., 2017, 56, 6749-6752.

[MIII2MII3]n+ trigonal bipyramidal cages based on diamagnetic and paramagnetic metalloligands

S. Sanz, H. M. O’Connor, V. Marti-Centelles, P. Comar, M. B. Pitak, S. J. Coles, G. Lorusso, E. Palacios, M. Evangelisti, A. Baldansuren, N. F. Chilton, H. Weihe, E. J. L. McInnes, P. J. Lusby, S. Piligkos and E. K. Brechin, Chem. Sci., 2017, 8, 5526-5535.

Investigation into the Effects of a Trigonal-Planar Ligand Field on the Electronic Properties of Lanthanide(II) Tris(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb)

C. A. P. Goodwin, N. F. Chilton, L. S. Natrajan, M.-E. Boulon, J. W. Ziller, W. J. Evans and D. P. Mills, Inorg. Chem., 2017, 56, 5959-5970.

Binding CO2 by a Cr8 Metallacrown

I. J. Vitorica-Yrezabal, D. F. Sava, G. A. Timco, M. S. Brown, M. Savage, H. G. W. Godfrey, F. Moreau, M. Schroder, F. Siperstein, L. Brammer, S. Yang, M. P. Attfield, J. J. W. McDouall and R. E. P. Winpenny, Angew. Chem. Int. Ed., 2017, 56, 5527-5530.

Exploring the Coordination Capabilities of a Family of Flexible Benzotriazole-Based Ligands Using Cobalt(II) Sources

E. Loukopoulos, N. F. Chilton, A. Abdul-Sada and G. E. Kostakis, Crystal Growth & Design, 2017, 17, 2718-2729.

Cu(II) Coordination Polymers as Vehicles in the A3 Coupling

E. Loukopoulos, M. Kallitsakis, N. Tsoureas, A. Abdul-Sada, N. F. Chilton, I. N. Lykakis and G. E. Kostakis, Inorg. Chem., 2017, 56, 4898-4910.

Measuring Spin...Spin Interactions between Heterospins in a Hybrid [2]Rotaxane

M.-E. Boulon, A. Fernandez, E. Moreno Pineda, N. F. Chilton, G. Timco, A. J. Fielding and R. E. P. Winpenny, Angew. Chem. Int. Ed., 2017, 56, 3876-3879.

Analysis of Lanthanide-Radical Magnetic Interactions in Ce(III) 2,2'-Bipyridyl Complexes

F. Ortu, J. Liu, M. Burton, J. M. Fowler, A. Formanuik, M.-E. Boulon, N. F. Chilton and D. P. Mills, Inorg. Chem., 2017, 56, 2496-2505.

Terminal Uranium(V/VI) Nitride Activation of Carbon Dioxide and Carbon Disulfide: Factors Governing Diverse and Well-Defined Cleavage and Redox Reactions

P. A. Cleaves, C. E. Kefalidis, B. M. Gardner, F. Tuna, E. J. L. McInnes, W. Lewis, L. Maron and S. T. Liddle, Chem. Eur. J., 2017, 23, 2950-2959.

Portraying entanglement between molecular qubits with four-dimensional inelastic neutron scattering

E. Garlatti, T. Guidi, S. Ansbro, P. Santini, G. Amoretti, J. Ollivier, H. Mutka, G. Timco, I. J. Vitorica-Yrezabal, G. F. S. Whitehead, R. E. P. Winpenny and S. Carretta, Nature Commun., 2017, 8, 14543.

Modulating supramolecular binding of carbon dioxide in a redox-active porous metal-organic framework

Z. Lu, H. G. W. Godfrey, I. da Silva, Y. Cheng, M. Savage, F. Tuna, E. J. L. McInnes, S. J. Teat, K. J. Gagnon, M. D. Frogley, P. Manuel, S. Rudi?, A. J. Ramirez-Cuesta, T. L. Easun, S. Yang and M. Schroder, Nature Commun., 2017, 8, 14212.

The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes

M. Gregson, E. Lu, D. P. Mills, F. Tuna, E. J. L. McInnes, C. Hennig, A. C. Scheinost, J. McMaster, W. Lewis, A. J. Blake, A. Kerridge and S. T. Liddle, Nature Commun., 2017, 8, 14137.

2016

Actinide covalency measured by pulsed electron paramagnetic resonance spectroscopy

A. Formanuik, A.-M. Ariciu, F. Ortu, R. Beekmeyer, A. Kerridge, F. Tuna, E. J. L. McInnes and D. P. Mills, Nature Chem., 2016, 9, 578–583.

On Approaching the Limit of Molecular Magnetic Anisotropy: A Near-Perfect Pentagonal Bipyramidal Dysprosium(III) Single-Molecule Magnet

Y.-S. Ding, N. F. Chilton, R. E. P. Winpenny and Y.-Z. Zheng, Angew. Chem. Int. Ed., 2016, 55, 16071–16074.

Molecular and electronic structure of terminal and alkali metal-capped uranium(V) nitride complexes

D. M. King, P. A. Cleaves, A. J. Wooles, B. M. Gardner, N. F. Chilton, F. Tuna, W. Lewis, E. J. L. McInnes and S. T. Liddle, Nature Commun., 2016, 7, 13773.

Synthesis, Electronic, Magnetic and Structural Characterization of New Trinuclear Mixed-Valence CoIII-CoII-CoIII Complex.

E. Baca-Solis, S. Bernes, H. Vazquez-Lima, M.-E. Boulon, R. E. P. Winpenny and Y. Reyes-Ortega, ChemistrySelect, 2016, 1, 6866–6871.

Antimony-ligated dysprosium single-molecule magnets as catalysts for stibine dehydrocoupling

T. Pugh, N. F. Chilton and R. A. Layfield, Chem. Sci., 2016, doi:10.1039/C6SC04465D.

Unprecedented hexagonal bipyramidal single-ion magnets based on metallacrowns

Q. W. Li, R. C. Wan, Y. C. Chen, J. L. Liu, L. F. Wang, J. H. Jia, N. F. Chilton and M.-L. Tong, Chem. Commun., 2016, 52, 13365–13368.

A Facile Synthetic Route to a Family of Mn III Monomers and Their Structural, Magnetic and Spectroscopic Studies: A Facile Synthetic Route to a Family of MnIII Monomers and Their Structural, Magnetic and Spectroscopic Studies

E. Houton, B. Kelly, S. Sanz, E. J. L. McInnes, D. Collison, E. K. Brechin, A.-L. Barra, A. G. Ryder and L. F. Jones, Eur. J. Inorg. Chem., 2016, 2016, 5123–5131.

Switchable Interaction in Molecular Double Qubits

J. Ferrando-Soria, S. A. Magee, A. Chiesa, S. Carretta, P. Santini, I. J. Vitorica-Yrezabal, F. Tuna, G. F. S. Whitehead, S. Sproules, K. M. Lancaster, A.-L. Barra, G. A. Timco, E. J. L. McInnes and R. E. P. Winpenny, Chem, 2016, 1, 727–752.

EPR Interactions - Coupled Spins

E. J. L. McInnes and D. Collison, eMagRes, 2016, 1445–1458.

A Low-Symmetry Dysprosium Metallocene Single-Molecule Magnet with a High Anisotropy Barrier

T. Pugh, N. F. Chilton and R. A. Layfield, Angew. Chem. Int. Ed., 2016, 55, 11082–11085.

[CrF(O2CtBu)2]9:Synthesis and Characterization of a Regular Homometallic Ring with an Odd Number of Metal Centers and Electrons

R. J. Woolfson, G. A. Timco, A. Chiesa, I. J. Vitorica-Yrezabal, F. Tuna, T. Guidi, E. Pavarini, P. Santini, S. Carretta and R. E. P. Winpenny, Angew. Chem. Int. Ed., 2016, 55, 8856–8859.

Tetranuclear Zn/4f coordination clusters as highly efficient catalysts for Friedel–Crafts alkylation

K. Griffiths, P. Kumar, G. R. Akien, N. F. Chilton, A. Abdul-Sada, G. J. Tizzard, S. J. Coles and G. E. Kostakis, Chem. Commun., 2016, 52, 7866–7869.

Physicochemical Properties of Near-Linear Lanthanide(II) Bis(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb)

C. A. P. Goodwin, N. F. Chilton, G. F. Vettese, E. Moreno Pineda, I. F. Crowe, J. W. Ziller, R. E. P. Winpenny, W. J. Evans and D. P. Mills, Inorg. Chem., 2016, doi:10.1021/acs.inorgchem.6b00808.

A modular design of molecular qubits to implement universal quantum gates

J. Ferrando-Soria, E. Moreno Pineda, A. Chiesa, A. Fernandez, S. A. Magee, S. Carretta, P. Santini, I. J. Vitorica-Yrezabal, F. Tuna, G. A. Timco, E. J. L. McInnes and R. E. P. Winpenny, Nature Commun., 2016, 7, 11377.

Three-Coordinate Iron(II) Expanded Ring N-Heterocyclic Carbene Complexes

J. J. Dunsford, D. J. Evans, T. Pugh, S. N. Shah, N. F. Chilton and M. J. Ingleson, Organometallics, 2016, 35, 1098–1106.

Evidence of Slow Magnetic Relaxation in Co(AcO)2(py)2(H2O)2

J. P. S. Walsh, G. Bowling, A.-M. Ariciu, N. F. M. Jailani, N. F. Chilton, P. G. Waddell, D. Collison, F. Tuna and L. J. Higham, Magnetochemistry, 2016, 2, 23.

Relaxation dynamics in the frustrated Cr9 antiferromagnetic ring probed by NMR

E. Garlatti, S. Bordignon, S. Carretta, G. Allodi, G. Amoretti, R. De Renzi, A. Lascialfari, Y. Furukawa, G. A. Timco, R. Woolfson, R. E. P. Winpenny and P. Santini, Phys. Rev. B, 2016, doi:10.1103/PhysRevB.93.024424.

Making hybrid [n]-rotaxanes as supramolecular arrays of molecular electron spin qubits

A. Fernandez, J. Ferrando-Soria, E. M. Pineda, F. Tuna, I. J. Vitorica-Yrezabal, C. Knappke, J. Ujma, C. A. Muryn, G. A. Timco, P. E. Barran, A. Ardavan and R. E. P. Winpenny, Nature Commun., 2016, 7, 10240.

Inter- versus Intramolecular Structural Manipulation of a Dichromium(II) Pacman Complex through Pressure Variation

C. J. Stevens, A. Prescimone, F. Tuna, E. J. L. McInnes, S. Parsons, C. A. Morrison, P. L. Arnold and J. B. Love, Inorg. Chem., 2016, 55, 214–220.

Copper Keplerates: High-Symmetry Magnetic Molecules

M. A. Palacios, E. Moreno Pineda, S. Sanz, R. Inglis, M. B. Pitak, S. J. Coles, M. Evangelisti, H. Nojiri, C. Heesing, E. K. Brechin, J. Schnack and R. E. P. Winpenny, Chem. Phys. Chem., 2016, 17, 55–60.

Studies of a Large Odd-Numbered Odd-Electron Metal Ring: Inelastic Neutron Scattering and Muon Spin Relaxation Spectroscopy of Cr8Mn

M. L. Baker, T. Lancaster, A. Chiesa, G. Amoretti, P. J. Baker, C. Barker, S. J. Blundell, S. Carretta, D. Collison, H. U. Güdel, T. Guidi, E. J. L. McInnes, J. S. M?ller, H. Mutka, J. Ollivier, F. L. Pratt, P. Santini, F. Tuna, P. L. W. Tregenna-Piggott, I. J. Vitorica-Yrezabal, G. A. Timco and R. E. P. Winpenny, Chem. Eur. J., 2016, 22, 1779–1788.

Synthesis and reactions of N-heterocycle functionalised variants of heterometallic {Cr7Ni} rings

G. F. S. Whitehead, J. Ferrando-Soria, L. Carthy, R. G. Pritchard, S. J. Teat, G. A. Timco and R. E. P. Winpenny, Dalton Trans., 2016, 45, 1638–1647.

Heterodimers of heterometallic rings

G. Timco, S. Marocchi, E. Garlatti, C. Barker, M. Albring, V. Bellini, F. Manghi, E. J. L. McInnes, R. G. Pritchard, F. Tuna, W. Wernsdorfer, G. Lorusso, G. Amoretti, S. Carretta, M. Affronte and R. E. P. Winpenny, Dalton Trans., 2016, 45, 16610–16615.

Observation of the influence of dipolar and spin frustration effects on the magnetocaloric properties of a trigonal prismatic {Gd7} molecular nanomagnet

E. M. Pineda, G. Lorusso, K. H. Zangana, E. Palacios, J. Schnack, M. Evangelisti, R. E. P. Winpenny and E. J. L. McInnes, Chem. Sci., 2016, 7, 4891–4895.

Emergence of comparable covalency in isostructural cerium(iv)- and uranium(iv)-carbon multiple bonds

M. Gregson, E. Lu, F. Tuna, E. J. L. McInnes, C. Hennig, A. C. Scheinost, J. McMaster, W. Lewis, A. J. Blake, A. Kerridge and S. T. Liddle, Chem. Sci., 2016, 7, 3286–3297.

A monometallic lanthanide bis(methanediide) single molecule magnet with a large energy barrier and complex spin relaxation behaviour

M. Gregson, N. F. Chilton, A.-M. Ariciu, F. Tuna, I. F. Crowe, W. Lewis, A. J. Blake, D. Collison, E. J. L. McInnes, R. E. P. Winpenny and S. T. Liddle, Chem. Sci., 2016, 7, 155–165.

2015

Low temperature magnetic properties and spin dynamics in single crystals of Cr8Zn antiferromagnetic molecular rings

F. Adelnia, A. Chiesa, S. Bordignon, S. Carretta, A. Ghirri, A. Candini, C. Cervetti, M. Evangelisti, M. Affronte, I. Sheikin, R. Winpenny, G. Timco, F. Borsa and A. Lascialfari, J. Chem. Phys., 2015, 143, 244321.

Comparison of spin dynamics and magnetic properties in antiferromagnetic closed and open molecular Cr-based rings

F. Adelnia, L. Bordonali, M. Mariani, S. Bordignon, G. Timco, R. Winpenny, F. Borsa and A. Lascialfari, J. Phys. Cond. Mat., 2015, 27, 506001.

Electronic Structure of a Mixed-Metal Fluoride-Centered Triangle Complex: A Potential Qubit Component

J. P. S. Walsh, S. B. Meadows, A. Ghirri, F. Moro, M. Jennings, W. F. Smith, D. M. Graham, T. Kihara, H. Nojiri, I. J. Vitorica-Yrezabal, G. A. Timco, D. Collison, E. J. L. McInnes and R. E. P. Winpenny, Inorg. Chem., 2015, 54, 12019–12026.

Coherent Spin Dynamics in Molecular Cr8Zn Wheels

A. Ghirri, A. Chiesa, S. Carretta, F. Troiani, J. van Tol, S. Hill, I. Vitorica-Yrezabal, G. A. Timco, R. E. P. Winpenny and M. Affronte, J. Phys. Chem. Lett., 2015, 6, 5062–5066.

Isolation of Elusive HAsAsH in a Crystalline Diuranium(IV) Complex

B. M. Gardner, G. Balázs, M. Scheer, A. J. Wooles, F. Tuna, E. J. L. McInnes, J. McMaster, W. Lewis, A. J. Blake and S. T. Liddle, Angew. Chem. Int. Ed., 2015, 54, 15250–15254.

Engineering coherent interactions in molecular nanomagnet dimers

A. Ardavan, A. M. Bowen, A. Fernandez, A. J. Fielding, D. Kaminski, F. Moro, C. A. Muryn, M. D. Wise, A. Ruggi, E. J. L. McInnes, K. Severin, G. A. Timco, C. R. Timmel, F. Tuna, G. F. S. Whitehead and R. E. P. Winpenny, npj Quant. Inf., 2015, doi:10.1038/npjqi.2015.12.

Heterometallic Rings: Their Physics and use as Supramolecular Building Blocks

E. J. L. McInnes, G. A. Timco, G. F. S. Whitehead and R. E. P. Winpenny, Angew. Chem. Int. Ed., 2015, 54, 14244–14269.

g-Engineering in Hybrid Rotaxanes To Create AB and AB2 Electron Spin Systems: EPR Spectroscopic Studies of Weak Interactions between Dissimilar Electron Spin Qubits

A. Fernandez, E. Moreno Pineda, C. A. Muryn, S. Sproules, F. Moro, G. A. Timco, E. J. L. McInnes and R. E. P. Winpenny, Angew. Chem. Int. Ed., 2015, 54, 10858–10861.

Spectroscopic and Crystal Field Consequences of Fluoride Binding by [Yb⋅DTMA]3+ in Aqueous Solution

O. A. Blackburn, N. F. Chilton, K. Keller, C. E. Tait, W. K. Myers, E. J. L. McInnes, A. M. Kenwright, P. D. Beer, C. R. Timmel and S. Faulkner, Angew. Chem. Int. Ed., 2015, 54, 10783–10786.

A Trigonal Prismatic Mononuclear Cobalt(II) Complex Showing Single-Molecule Magnet Behavior

V. V. Novikov, A. A. Pavlov, Y. V. Nelyubina, M.-E. Boulon, O. A. Varzatskii, Y. Z. Voloshin and R. E. P. Winpenny, J. Am. Chem. Soc., 2015, 137, 9792–9795.

Copper Lanthanide Phosphonate Cages: Highly Symmetric {Cu3Ln9P6} and {Cu6Ln6P6} Clusters with C3 v and D3h Symmetry

E. Moreno Pineda, C. Heesing, F. Tuna, Y.-Z. Zheng, E. J. L. McInnes, J. Schnack and R. E. P. Winpenny, Inorg. Chem., 2015, 54, 6331–6337.

Influencing the properties of dysprosium single-molecule magnets with phosphorus donor ligands

T. Pugh, F. Tuna, L. Ungur, D. Collison, E. J. L. McInnes, L. F. Chibotaru and R. A. Layfield, Nature Commun., 2015, 6, 7492.

Microstrip Resonators and Broadband Lines for X-band EPR Spectroscopy of Molecular Nanomagnets

A. Ghirri, C. Bonizzoni, M. Righi, F. Fedele, G. Timco, R. Winpenny and M. Affronte, Appl. Magn. Reson., 2015, 46, 749–756.

Triamidoamine uranium(IV)–arsenic complexes containing one-, two- and threefold U–As bonding interactions

B. M. Gardner, G. Balázs, M. Scheer, F. Tuna, E. J. L. McInnes, J. McMaster, W. Lewis, A. J. Blake and S. T. Liddle, Nat Chem, 2015, 7, 582–590.

Controlled Synthesis of Nanoscopic Metal Cages

J. Ferrando-Soria, A. Fernandez, E. Moreno Pineda, S. A. Varey, R. W. Adams, I. J. Vitorica-Yrezabal, F. Tuna, G. A. Timco, C. A. Muryn and R. E. P. Winpenny, J. Am. Chem. Soc., 2015, 137, 7644–7647.

An Inverted-Sandwich Diuranium μ-η5:η5-Cyclo-P5 Complex Supported by U-P5 δ-Bonding

B. M. Gardner, F. Tuna, E. J. L. McInnes, J. McMaster, W. Lewis, A. J. Blake and S. T. Liddle, Angew. Chem. Int. Ed., 2015, 54, 7068–7072.

[CrIII8MII6]12+ Coordination Cubes (MII=Cu,Co)

S. Sanz, H. M. O’Connor, E. M. Pineda, K. S. Pedersen, G. S. Nichol, O. M?nsted, H. Weihe, S. Piligkos, E. J. L. McInnes, P. J. Lusby and E. K. Brechin, Angew. Chem. Int. Ed., 2015, 54, 6761–6764.

Systematic Study of a Family of Butterfly-Like {M2Ln2} Molecular Magnets (M = MgII, MnIII, CoII, NiII, and CuII; Ln = YIII, GdIII, TbIII, DyIII, HoIII, and ErIII)

E. Moreno Pineda, N. F. Chilton, F. Tuna, R. E. P. Winpenny and E. J. L. McInnes, Inorg. Chem., 2015, doi:10.1021/acs.inorgchem.5b00746.

Direct observation of finite size effects in chains of antiferromagnetically coupled spins

T. Guidi, B. Gillon, S. A. Mason, E. Garlatti, S. Carretta, P. Santini, A. Stunault, R. Caciuffo, J. van Slageren, B. Klemke, A. Cousson, G. A. Timco and R. E. P. Winpenny, Nature Commun., 2015, 6, 7061.

High temperature spin dynamics in linear magnetic chains, molecular rings, and segments by nuclear magnetic resonance

F. Adelnia, M. Mariani, L. Ammannato, A. Caneschi, D. Rovai, R. Winpenny, G. Timco, M. Corti, A. Lascialfari and F. Borsa, J. Appl. Phys., 2015, 117, 17B308.

Molecular and electronic structures of donor-functionalized dysprosium pentadienyl complexes

B. M. Day, N. F. Chilton and R. A. Layfield, Dalton Trans., 2015, 44, 7109–7113.

Crystal structure of diethyl 2,2’-[((1E,1’E)-{[(1R,4R)-cyclo­hexane-1,4-di­yl]bis­(aza­nylyl­idene)}bis­(methanylyl­idene))bis­(1H-pyrrole-2,1-di­yl)]di­acetate

J. Alshawi, M. Yousif, K. H. Zangana, I. J. Vitorica Yrezabal, R. Winpenny and M. J. Al-Jeboori, Acta Cryst. E, 2015, 71, o165–o166.

Design Criteria for High-Temperature Single-Molecule Magnets

N. F. Chilton, Inorg. Chem., 2015, 54, 2097–2099.

Single molecule magnet behaviour in a {Dy4P2} octahedron

K. H. Zangana, E. Moreno Pineda and R. E. P. Winpenny, Dalton Trans., 2015, 44, 12522–12525.

An extended framework of cages formed of pre-synthesised and functionalised heterometallic cages

G. F. S. Whitehead, S. J. Teat, K. J. Gagnon, G. A. Timco and R. E. P. Winpenny, Chem. Commun., 2015, 51, 3533–3536.

Platinum(ii) complexes of mixed-valent radicals derived from cyclotricatechylene, a macrocyclic tris-dioxolene

J. J. Loughrey, N. J. Patmore, A. Baldansuren, A. J. Fielding, E. J. L. McInnes, M. J. Hardie, S. Sproules and M. A. Halcrow, Chem. Sci., 2015, 6, 6935–6948.

Binary behaviour of an oxidation-responsive MRI nano contrast agent

D. Jeanmaire, G. A. Timco, A. Gennari, S. Sproules, K. J. Williams, R. E. P. Winpenny and N. Tirelli, Chem. Commun., 2015, 51, 1074–1076.

Discrete and polymeric cobalt organophosphates: isolation of a 3-D cobalt phosphate framework exhibiting selective CO2 capture

S. K. Gupta, S. Kuppuswamy, J. P. S. Walsh, E. J. L. McInnes and R. Murugavel, Dalton Trans., 2015, 44, 5587–5601.

Effects of the Dzyaloshinskii-Moriya interaction in Cr3 triangular spin clusters detected by specific heat and multi-frequency electron spin resonance

A. Ghirri, J. van Tol, I. Vitorica-Yrezabal, G. A. Timco and R. E. P. Winpenny, Dalton Trans., 2015, 44, 14027–14033.

A hybrid organic–inorganic molecular daisy chain

A. Fernandez, E. Moreno Pineda, J. Ferrando-Soria, E. J. L. McInnes, G. A. Timco and R. E. P. Winpenny, Chem. Commun., 2015, 51, 11126–11129.

Ligand field influence on the electronic and magnetic properties of quasi-linear two-coordinate iron(ii) complexes

N. F. Chilton, H. Lei, A. M. Bryan, F. Grandjean, G. J. Long and P. P. Power, Dalton Trans., 2015, 44, 11202–11211.

The first near-linear bis(amide) f-block complex: a blueprint for a high temperature single molecule magnet

N. F. Chilton, C. A. P. Goodwin, D. P. Mills and R. E. P. Winpenny, Chem. Commun., 2015, 51, 101–103.

2014

Quantum spin coherence in halogen-modified Cr7 Ni molecular nanomagnets

D. Kaminski, A. L. Webber, C. J. Wedge, J. Liu, G. A. Timco, I. J. Vitorica-Yrezabal, E. J. L. McInnes, R. E. P. Winpenny and A. Ardavan, Phys. Rev. B, 2014, doi:10.1103/PhysRevB.90.184419.

[UIII{N(SiMe2tBu2}3]: A Structurally Authenticated Trigonal Planar Actinide Complex

C. A. P. Goodwin, F. Tuna, E. J. L. McInnes, S. T. Liddle, J. McMaster, I. J. Vitorica-Yrezabal and D. P. Mills, Chem. Eur. J., 2014, 20, 14579–14583.

Quantum signatures of a molecular nanomagnet in direct magnetocaloric measurements

J. W. Sharples, D. Collison, E. J. L. McInnes, J. Schnack, E. Palacios and M. Evangelisti, Nature Commun., 2014, 5, 5321.

Direct measurement of dysprosium(III)···dysprosium(III) interactions in a single-molecule magnet

E. Moreno Pineda, N. F. Chilton, R. Marx, M. Dörfel, D. O. Sells, P. Neugebauer, S.-D. Jiang, D. Collison, J. van Slageren, E. J. L. McInnes and R. E. P. Winpenny, Nature Commun., 2014, 5, 5243.

Two-Electron Reductive Carbonylation of Terminal Uranium(V) and Uranium(VI) Nitrides to Cyanate by Carbon Monoxide

P. A. Cleaves, D. M. King, C. E. Kefalidis, L. Maron, F. Tuna, E. J. L. McInnes, J. McMaster, W. Lewis, A. J. Blake and S. T. Liddle, Angew. Chem. Int. Ed., 2014, 53, 10412–10415.

On the Possibility of Magneto-Structural Correlations: Detailed Studies of Dinickel Carboxylate Complexes

J. P. S. Walsh, S. Sproules, N. F. Chilton, A.-L. Barra, G. A. Timco, D. Collison, E. J. L. McInnes and R. E. P. Winpenny, Inorg. Chem., 2014, 53, 8464–8472.

Linking Cr 3 triangles through phosphonates and lanthanides: synthetic, structural, magnetic and EPR studies

K. H. Zangana, E. M. Pineda, I. J. Vitorica-Yrezabal, E. J. L. McInnes and R. E. P. Winpenny, Dalton Trans., 2014, 43, 13242.

A Detailed Study of the Magnetism of Chiral {Cr7M} Rings: An Investigation into Parametrization and Transferability of Parameters

E. Garlatti, M. A. Albring, M. L. Baker, R. J. Docherty, H. Mutka, T. Guidi, V. Garcia Sakai, G. F. S. Whitehead, R. G. Pritchard, G. A. Timco, F. Tuna, G. Amoretti, S. Carretta, P. Santini, G. Lorusso, M. Affronte, E. J. L. McInnes, D. Collison and R. E. P. Winpenny, J. Am. Chem. Soc., 2014, 136, 9763–9772.

Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex

E. Lu, O. J. Cooper, J. McMaster, F. Tuna, E. J. L. McInnes, W. Lewis, A. J. Blake and S. T. Liddle, Angew. Chem. Int. Ed., 2014, 53, 6696–6700.

Magnetic anisotropy of polycrystalline magnetoferritin investigated by SQUID and electron magnetic resonance

F. Moro, R. de Miguel, M. Jenkins, C. Gómez-Moreno, D. Sells, F. Tuna, E. J. L. McInnes, A. Lostao, F. Luis and J. van Slageren, J. Magn. Magn. Mater., 2014, 361, 188–196.

Large Zero-Field Splittings of the Ground Spin State Arising from Antisymmetric Exchange Effects in Heterometallic Triangles

S. A. Magee, S. Sproules, A.-L. Barra, G. A. Timco, N. F. Chilton, D. Collison, R. E. P. Winpenny and E. J. L. McInnes, Angew. Chem. Int. Ed., 2014, 53, 5310–5313.

Stable Mixed-Valent Radicals from Platinum(II) Complexes of a Bis(dioxolene) Ligand

J. J. Loughrey, S. Sproules, E. J. L. McInnes, M. J. Hardie and M. A. Halcrow, Chem. Eur. J., 2014, 20, 6272–6276.

Triamidoamine–Uranium(IV)-Stabilized Terminal Parent Phosphide and Phosphinidene Complexes

B. M. Gardner, G. Balázs, M. Scheer, F. Tuna, E. J. L. McInnes, J. McMaster, W. Lewis, A. J. Blake and S. T. Liddle, Angew. Chem. Int. Ed., 2014, 53, 4484–4488.

Synthesis and Characterization of an f-Block Terminal Parent Imido [U═NH] Complex: A Masked Uranium(IV) Nitride

D. M. King, J. McMaster, F. Tuna, E. J. L. McInnes, W. Lewis, A. J. Blake and S. T. Liddle, J. Am. Chem. Soc., 2014, 136, 5619–5622.

Iron Lanthanide Phosphonate Clusters: {Fe6Ln6P6} Wells-Dawson-like Structures with Dsub>3d Symmetry

E. M. Pineda, F. Tuna, Y.-Z. Zheng, S. J. Teat, R. E. P. Winpenny, J. Schnack and E. J. L. McInnes, Inorg. Chem., 2014, 53, 3032–3038.

Centred nine-metal rings of lanthanides

K. H. Zangana, E. M. Pineda, E. J. L. McInnes, J. Schnack and R. E. P. Winpenny, Chem. Commun., 2014, 50, 1438–1440.

The acid test: the chemistry of carboxylic acid functionalised {Cr7Ni} rings

G. F. S. Whitehead, J. Ferrando-Soria, L. G. Christie, N. F. Chilton, G. A. Timco, F. Moro and R. E. P. Winpenny, Chem. Sci., 2014, 5, 235–239.

Synthesis and magnetothermal properties of a ferromagnetically coupled NiII–GdIII–NiII cluster

A. Upadhyay, N. Komatireddy, A. Ghirri, F. Tuna, S. K. Langley, A. K. Srivastava, E. C. Sañudo, B. Moubaraki, K. S. Murray, E. J. L. McInnes, M. Affronte and M. Shanmugam, Dalton Trans., 2014, 43, 259–266.

The coordination chemistry of tartronic acid with copper: magnetic studies of a quasi-equilateral tricopper triangle

G. Pascu, C. Deville, S. E. Clifford, L. Guenée, C. Besnard, K. W. Krämer, S.-X. Liu, S. Decurtins, F. Tuna, E. J. L. McInnes, R. E. P. Winpenny and A. F. Williams, Dalton Trans., 2014, 43, 656–662.

Coherent electron spin manipulation in a dilute oriented ensemble of molecular nanomagnets: pulsed EPR on doped single crystals

F. Moro, D. Kaminski, F. Tuna, G. F. S. Whitehead, G. A. Timco, D. Collison, R. E. P. Winpenny, A. Ardavan and E. J. L. McInnes, Chem. Commun., 2014, 50, 91–93.

Cluster-Based Single-Molecule Magnets

C. J. Milios and R. E. P. Winpenny, Molecular Nanomagnets and Related Phenomena, 2014, 164, 1–109.

Fast magnetic relaxation in an octahedral dysprosium tetramethyl-aluminate complex

S. N. König, N. F. Chilton, C. Maichle-Mössmer, E. M. Pineda, T. Pugh, R. Anwander and R. A. Layfield, Dalton Trans., 2014, 43, 3035–3038.

2013

A Dense Metal–Organic Framework for Enhanced Magnetic Refrigeration

G. Lorusso, J. W. Sharples, E. Palacios, O. Roubeau E. K. Brechin, R. Sessoli, A. Rossin, F. Tuna, E. J. L. McInnes, D. Collison and M. Evangelisti, Adv. Mater., 2013, 25, 4653–4656.

Wells-Dawson cages as molecular refrigerants

E. M. Pineda, F. Tuna, Y. -Z. Zheng, R. E. P. Winpenny and E. J. L. McInnes, Inorg. Chem., 2013, 52, 13702–13707.

The acid test: the chemistry of carboxylic acid functionalised {Cr₇Ni} rings

G. F. S. Whitehead, J. Ferrando-Soria, L. G. Christie, N. F. Chilton, G. A. Timco, F. Moro and R. E. P. Winpenny, Chem. Sci., 2014, 5, 235–239.

Fast magnetic relaxation in an octahedral dysprosium tetramethyl-aluminate complex

S. N. König, N. F. Chilton, C. Maichle-Mössmer, E. M. Pineda, T. Pugh, R. Anwander and R. A. Layfield, Dalton Trans., 2013, (Accepted).

An electrostatic model for the determination of magnetic anisotropy in dysprosium complexes

N. F. Chilton, D. Collison, E. J. L. McInnes, R. E. P. Winpenny and A. Soncini, Nat. Commun., 2013, 4, 2551.

Octametallic 4f-phosphonate horseshoes

K. H. Zangana, E. M. Pineda, J. Schnack and R. E. P. Winpenny, Dalton Trans., 2013, 42, 14045–14048.

A ring of rings and other multicomponent assemblies of cages

G. F. S. Whitehead, F. Moro, G. A. Timco, W. Wernsdorfer, S. J. Teat and R. E. P. Winpenny, Angew. Chem. Int. Ed., 2013, 52, 9932–9935.

Magnetic relaxation pathways in lanthanide single-molecule magnets

R. J. Blagg, L. Ungur, F. Tuna, J. Speak, P. Comar, D. Collison, W. Wernsdorfer, E. J. L. McInnes L. F. Chibotaru and R. E. P. Winpenny, Nat. Chem., 2013, 5, 673–678.

Rings and threads as linkers in metal-organic frameworks and poly-rotaxanes

G. F. S. Whitehead, B. Cross, L. Carthy, V. A. Milway, H. Rath, A. Fernandez, S. L. Heath, C. A. Muryn, R. G. Pritchard, S. J. Teat, G. A. Timco and R. E. P. Winpenny, Chem. Commun., 2013, 49, 7195–7197.

Detection of ground states in frustrated molecular rings by the in-field local magnetization profiles

M. Antkowiak, P. Kozlowski, G. Kamieniarz, G. A. Timco, F. Tuna and R. E. P. Winpenny, Phys. Rev. B., 2013, 87, 184430.

Lanthanide single-molecule magnets

R. A. Layfield, R. E. P. Winpenny and D. Woodruff, Chem. Rev., 2013, 113, 5110–5148.

The nature of the U=C double bond: Pushing the stability of high-oxidation-state carbened to the limit

O. J. Cooper, D. P. Mills, J. McMaster, F. Tuna, E. J. L. McInnes, W. Lewis, A. J. Blake and S. T. Liddle, Chem. Eur. J., 2013, 19, 7071–7083.

Single-molecule magnetism in a single-ion triamidoamine uranium(V) terminal mono-oxo complex

D. M. King, F. Tuna, J. McMaster, W. Lewis, A. J. Blake, E. J. L. McInnes and S. T. Liddle, Angew. Chem. Int. Ed., 2013, 52, 4921–4924.

Magnetic cooling at a single molecule level: A spectroscopic investigation of isolated molecules on a surface

V. Corradini, A. Ghirri, A. Candini, R. Biagi, U. del Pennino, G. Dotti, E. Otero, F. Choueikani, R. J. Blagg, E. J. L. McInnes and M. Affronte, Adv. Mater., 2013, 25, 2816–2820.

Studies of hybrid organic-inorganic [2] and [3] rotaxanes bound to Au surfaces

H. Rath, G. A. Timco,V. Corradini, A. Ghirri, U. del Pennino, A. Fernandez, R. G. Pritchard, C. A. Muryn, M. Affronte and R. E. P. Winpenny, Chem. Commun., 2013, 4, 3404–3406.

An {Fe₁₆} barrel: synthesis, structural and magnetic characterisation of an {Fe₈} ring and its dimer

I. Casson, C. A. Muryn, F. Tuna, J. Schnack and R. E. P. Winpenny, Polyhedron, 2013, 64 (special issue in honour of Prof G. Christou), 59–62.

Molecular amino-phosphonate cobalt-lanthanide clusters

E. M. Pineda, F. Tuna, R. G. Pritchard, A. C. Regan, Y. -Z. Zheng, R. E. P. Winpenny and E. J. L. McInnes, Chem. Commun., 2013, 49, 3522–3524.

A hydride-ligated dysprosium single-molecule magnet

A. Venugopal, F. Tuna, T. P. Spaniol, L. Ungur, L. F. Chibotaru, J. Okuda and R. A. Layfield, Chem. Commun., 2013, 49, 901–903.

Stretch for a moment

R. E. P. Winpenny, Nat. Nanotech., 2013, 8, 159–160 (highlight).

Single-molecule magnetism in tetrametallic terbium and dysprosium thiolate-bridged cages

D. N. Woodruff, F. Tuna, M. Bodensteiner, R. E. P. Winpenny and R. A. Layfield, Organometallics, 2013, 32, 1224–1229.

Isolation and characterization of a uranium(VI)-nitride triple bond

D. M. King, F. Tuna, E. J. L. McInnes, J. McMaster, W. Lewis, A. J. Blake and S. T. Liddle, Nat. Chem., 2013, 5 482–488.

Exchange-coupled oxygen- and sulfur-bridged cyclopentadienyl-manganese(II) cages

C. A. Smith, F. Tuna, M. Bodensteiner, M. Helliwell, D. Collison and R. A. Layfield, Dalton Trans., 2013, 42, 71–74.

Physical studies of heterometallic rings: An ideal system for studying magnetically-coupled systems

G. A. Timco, E. J. L. McInnes and R. E. P. Winpenny, Chem. Soc. Rev., 2013, 42, 1796–1806.

Synthesis of monodispersed magnetite nanoparticles from iron pivalate clusters

K. Abdulwahab, M. A. Malik, P. O’Brien, K. Govender, C. A. Muryn, G. A. Timco, F. Tuna and R. E. P. Winpenny, Dalton. Trans., 2013, 42, 196–206.

Coordination compounds and the magnetocaloric effect

J. W. Sharples and D. Collison, Polyhedron, 2013, 54, 91–103.

Pressure versus temperature effects on intramolecular electron transfer in mixed-valence complexes

S. Scheins, J. Overgaard, G. A. Timco, A. Stash, Y.-S. Chen, F. K. Larsen, M. Christensen, M. R. V. Jørgensen, S. R. Madsen, M. S. Schmøkel and B. B. Iversen, Chem. Eur. J., 2013, 19, 195–205.

2012

A classification of spin frustration in molecular magnets from a physical study of large odd-numbered-metal, odd electron rings

M. L. Baker, G. A. Timco, S. Piligkos, J. S. Mathieson, H. Mutka, F. Tuna, P. Kozlowski, M. Antkowiak, T. Guidi, T. Gupta, H. Rath, R. J. Woolfson, G. Kamieniarz, R. G. Pritchard, H. Weihe, L. Cronin, G. Rajaraman, D. Collison, E. J. L. McInnes and R. E. P. Winpenny, P. Natl. Acad. Sci. USA, 2012, DOI:10.1073/pnas.1213127109.

Spin dynamics of molecular nanomagnets unravelled at atomic scale by four-dimensional inelastic neutron scattering

M. L. Baker, T. Guidi, S. Carretta, H. Mutka, G. Timco, E. J. L. McInnes, G. Amoretti, R. E. P. Winpenny and P. Santini, Nat. Phys., 2012, DOI:10.1038/nphys2431.

Magnetic anisotropy of Cr₇Ni spin clusters on surfaces

V. Corradini, A. Ghirri, E. Garlatti, R. Biagi, V. De Renzi, U. del Pennino, V. Bellini, S. Carretta, P. Santini, G. Timco, R. E. P. Winpenny and M. Affronte, Adv. Funct. Mater., 2012, 22, 3706–3713.

Synthesis and characterisation of cobalt(II) phosphonate cage complexes utilizing carboxylates and pyridonates as co-ligands

S. K. Langley, M. Helliwell, S. J. Teat and R. E. P. Winpenny, Dalton Trans., 2012, 41, 12807–12817.

Synthesis, structure, and paramagnetism of manganese(II) iminophosphate complexes

D. Woodruff, E. J. L. McInnes, D. Sells, R. E. P. Winpenny and R. A. Layfield, Inorg. Chem., 2012, 51 (16), 9104–9109.

Metal phosphonate chemistry: From synthesis to applications (Editors: A. Clearfield and K. Demadis)

Royal Society of Chemistry, Cambridge, 2012, 364–419.

Local spin density in the Cr₇Ni antiferromagnetic molecular ring and ⁵³Cr-NMR

C. M. Casadei, L. Bordonali, Y. Furukawa, F. Borsa, E. Garlatti, A. Lascialfari, S. Carretta, S. Sanna, G. Timco and R. E. P. Winpenny, J. Phys. Cond. Matter., 2012, 24, 406002.

Inelastic neutron scattering studies on the odd-membered antiferromagnetic wheel Cr₈Ni

M. L. Baker, O. Waldmann, S. Piligkos, R. Bircher, O. Cador, S. Carretta, D. Collison, F. Fernandez-Alonso, E. J. L. McInnes, H. Mutka, A. Podlesnyak, F. Tuna, S. Ochsenbein, R. Sessoli, A. Sieber, G. A. Timco, H. Weihe, H. U. Güdel and R. E. P. Winpenny, Phys. Rev. B., 2012, 86, 064405.

Solvothermal preparation of iron phosphonate cages

Y-. Z. Zheng and R. E. P. Winpenny, Sci. China Chem., 2012, 55, 910–913.

Controlling magnetic communication through aromatic bridges by variation in torsion angle

T. B. Faust, F. Tuna, G. A. Timco, M. Affronte, V. Bellini, W. Wernsdorfer and R. E. P. Winpenny, Dalton Trans., 2012, 41, 13626–13631.

A high anisotropy barrier in a sulfur-bridged organodysprosium single-molecule magnet

F. Tuna, C. A. Smith, M. Bodensteiner, L. Ungur, L. F. Chibotaru, E. J. L. McInnes, R. E. P. Winpenny, D. Collison and R. A. Layfield, Angew. Chem. Int. Edit., 2012, 51, 6976–6980.

Syntheses, X-ray structural characterizations, and thermal stabilities of two nonclassical trinuclear vanadium(IV) complexes

J. S. Maass, Z. C. Chen, M. Zeller, F. Tuna, R. E. P. Winpenny and R. L. Luck, Inorg. Chem., 2012, 51, 2766–2776.

Mn(II)-Gd(III) phosphonate cages with a large magnetocaloric effect

Y. Zheng, E. Moreno Pineda, M. Helliwell and R. E. P. Winpenny, Chem. Eur. J., 2012, 18, 4161–4165.

Chemical engineering of molecular qubits

C. J. Wedge, R. E. George, G. A. Timco, F. Tuna, S. Rigby, E. J. L. McInnes, R. E. P. Winpenny, S. J. Blundell and A. Ardavan, Phys. Rev. Lett., 2012, 108, 107204.

Co–Ln mixed-metal phosphonate grids and cages as molecular magnetic refrigerants

Y. Zheng, M. Evangelisti, F. Tuna and R. E. P. Winpenny, J. Amer. Chem. Soc., 2012, 134, 1057–1065.

Single-molecule magnetism in cyclopentadienyl-dysprosium chlorides

S. Sulway, R. A. Layfield, F. Tuna, W. Wernsdorfer and R. E. P. Winpenny, Chem. Commun., 2012, 48, 1508–1510.